主成分分析法在油荧光光谱波段选择中的应用   总被引：5，自引：0，他引：5  

刘智深  丁宁  赵朝方  齐敏珺 《地理空间信息》2009,7(3):12-15

355nm激光器发射激光入射到海水表面，激发海表面溢油的荧光光谱，运用高光谱图像降维中应用广泛的分段主成分分析算法对油荧光光谱进行波段选择。该算法把每个分段被映射到主成分的信息量的大小作为是否被选择的标准，保证了选择波段的信息丰富；通过分段分析消除了传统主成分分析的全局性引起的波段忽略问题，获得较为满意的降维效果。  相似文献   

Field Detection of Chiorophyll-a Concentration in the Sea Surface Layer by an Airborne Oceanographic Lidar   总被引：2，自引：0，他引：2  

LIU Zhishen MA Sen WANG Xin LI Zhigang 《中国海洋大学学报(英文版)》2008,7(1):108-112

An airborne oceanographic lidar, with a frequency-tripled Q-switched Nd： YAG laser of 355 nm, has been designed to measure chlorophyll-a （Chl-a） concentration in the sea surface layer by the Ocean Remote Sensing Institute, OUC. The field experiment was carried out in the bay which is located south of the Liaodong Peninsula on the 10th of September 2005. After the flight, the raw data were processed and analyzed by the fluorescence-to-Raman ratio method with seawater attenuation coefficients calculated from signal profiles. The results of Chl-a concentration sea water were also compared with those of Chl-a concentration by measurements by lidar are shown. The measurements in clear a Moderate Resolution Imaging Spectroradiometer （MODIS）.  相似文献   

Continuous fluorescence assessment of organic matter variability on the Bournbrook River,Birmingham, UK     

Elfrida M. Carstea  Andy Baker  Gabriela Pavelescu  Ian Boomer 《水文研究》2009,23(13):1937-1946

Continuous monitoring of dissolved organic matter (DOM) character and concentration at hourly resolution is rare, despite the importance of analysing organic matter variability at high‐temporal resolution to evaluate river carbon budgeting, river water health by detecting episodic pollution and to determine short‐term variations in chemical and ecological function. The authors report a 2‐week experiment performed on DOM sampled from Bournbrook, Birmingham, UK, an urban river for which spectrophotometric (fluorescence, absorbance), physiochemical (dissolved organic carbon [DOC], electrical conductivity, pH) and isotopic (D/H) parameters have been measured at hourly frequency. Our results show that the river had sub‐daily variations in both organic matter concentration and characteristics. In particular, after relatively high‐magnitude precipitation events, organic carbon concentration increased, with an associated increase in intensity of both humic‐like and tryptophan‐like fluorescence. D/H isotopic ratio demonstrates different hydrological responses to different rainfall events, and organic matter character reflects this difference. Events with precipitation < 2 mm typically yielded isotopically heavy water with relatively hydrophilic DOM and relatively low specific absorbance. Events with precipitation > 2 mm had isotopically lighter water with higher specific absorbance and a decrease in the proportion of microbially derived to humic‐like fluorescence. In our heavily urbanized catchment, we interpret these signals as one where riverine DOM is dominated by storm sewer‐derived ‘old’ organic matter at low‐rainfall amounts and a mixed signal at high‐precipitation amounts where ‘event’ surface runoff‐derived organic matter dominate during storm sewer and combined sewer overflow routed DOM. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

RESOLUTION OF MULTICOMPONENT FLUORESCENT MIXTURES BY ANALYSIS OF THE EXCITATION-EMISSION-FREQUENCY ARRAY     

DONALD S.BURDICK XIN M.TU Institute of Statistics  Decision Sciences  Department of Mathematics Duke University  Durham  NC  U.S.A.LINDA B.MCGOWN DAVID W.MILLICAN Department of Chemistry  Drake University  Durham  NC  U.S.A. 《地理学报(英文版)》1990,(1)

Fluorescence lifetime provides a third independent dimension of information for the resolution of totalluminescence spectra of multicomponent mixtures.The incorporation of this parameter into theexcitation-emission matrix(EEM)by the phase modulation technique results in a three-dimensionalexcitation-emission-frequency array (EEFA).Multicomponent analysis based on the three-dimensionalEEFA brings a qualitative change for the resolved spectra,i.e.individual spectra can be uniquely resolved,which is impossible with any two-dimensional analysis.In this paper we present a method for analyzingthe EEFA.We show mathematically that with the three-dimensional analysis of the EEFA individualspectra and lifetimes can be obtained.Our algorithm is developed in mathematical detail and isdemonstrated by its application to a two-component mixture.  相似文献   

水面菲涅尔反射对~761 nm叶绿素荧光估算的影响     

温颜沙  邓建明  毛志华  石静  周杨  鲁婷  陆应诚 《遥感学报》2018,22(3):424-431

叶绿素荧光是光合作用的有效探针,可用于海洋浮游植物的监测与定量评估。太阳诱导叶绿素荧光覆盖可见光—近红外650—800 nm,在～685 nm与～740 nm表现出两个形态不同的荧光峰特征。基于～685 nm荧光峰的叶绿素浓度反演算法较为成熟,但在高悬浮物和高叶绿素浓度的水体中,算法的有效性不足。基于叶绿素荧光在氧气吸收谱段(O2-A)的填充作用,水体遥感反射率光谱～761 nm峰值中包含有太阳诱导叶绿素荧光信号,能用于水体叶绿素浓度的估算,但该反射峰形态特征还取决于传感器的光谱分辨率。本研究基于不同光谱分辨率的大气吸收谱线特征,模拟了水体遥感反射率光谱(750—775 nm)上太阳诱导叶绿素荧光的信号响应特征;分析了利用遥感反射率(～761 nm)计算叶绿素荧光的原理,阐明了不同光谱分辨率条件下水体叶绿素荧光信号在反射光谱上的形态变化规律。采用水面以上测量法获取的离水光谱辐亮度,包含了水面的菲涅尔反射信号,由于真实的菲涅尔系数难以准确测量,这给基于～761 nm处遥感反射率峰值的荧光信号估算带来不确定性影响。研究表明,假定菲涅尔系数为0时,虽然～761 nm叶绿素荧光信号与其浓度具有较好的线性统计关系,但却带来较大的不确定性;这种不确定的影响,在低浓度叶绿素水体中表现明显,在高浓度叶绿素水体中,影响相对较小;准确估算菲涅尔系数,有助于减少这种不确定性影响。对基于遥感反射率～761 nm叶绿素荧光信号的深入探讨,将能推动未来水体叶绿素荧光的识别与利用。  相似文献   

四川昭觉县中部乡镇表层土壤硒地球化学特征     

赵辰  孙彬彬  贺灵  吴超  成晓梦  曾道明  刘冬 《岩矿测试》2022,(3):412-426

硒元素是人体必需的微量元素之一,食用富硒农产品是人体获取和补充硒元素的主要途径,调查区域硒地球化学特征是有效地利用富硒土地资源以及开发富硒农副产品的重要依据。本文选择四川省昭觉县域内较为重要的农耕乡镇采集表层土壤样品,采用原子荧光光谱法、X射线荧光光谱法、电感耦合等离子体质谱/发射光谱法等方法测定1328件土壤、19件玉米及20件土豆中硒等地球化学指标含量,利用相关分析与统计学等方法,结合距离加权反比插值法,探讨研究区硒含量、分布和影响因素等地球化学特征,评价土壤与作物的富硒情况及安全性。结果表明：(1)研究区表层土壤硒含量范围为0.04～1.50mg/kg,平均值为0.33mg/kg,划定富硒土壤面积为7.23km~2,占全区土壤面积的30.31%,玄武岩发育的土壤硒含量最高,平均值为0.4mg/kg,表明区内地质背景与土壤硒含量密切相关,区内富硒土壤主要受含玄武岩夹苦橄岩、凝灰质砂泥岩的峨眉山玄武岩组地层控制;(2)不同的用地类型和土壤类型对硒元素的富集能力不同,人为农业活动导致土壤对硒的吸附能力下降,黄棕壤土层中黏粒或铁氧化物等易与硒结合富集;酸性土壤中硒含量与pH值成反比;土壤...  相似文献   

CdTe量子点荧光猝灭法测定赤泥中痕量镍     

欧阳振中  白珊  罗道成 《岩矿测试》2015,34(2):176-180

Cd Te量子点具有荧光强度高和稳定性好的优点,应用Cd Te量子点荧光猝灭法分析基体复杂的样品,需要有效分离对测定干扰的金属元素和高效富集待测元素。本文以巯基乙酸(TGA)作稳定剂,采用水相合成法制备了巯基乙酸修饰的Cd Te量子点,基于镍离子在p H=10.0硼砂缓冲溶液中对Cd Te量子点的荧光具有较强猝灭作用,建立了一种测定赤泥中痕量镍的荧光光度方法。荧光猝灭反应的最佳实验条件为:Cd Te量子点的浓度3.0×10-4mol/L,反应温度为室温,反应时间10 min,在此条件下镍离子浓度在2.0×10-7~7.8×10-5mol/L范围内与Cd Te量子点的相对荧光强度呈良好的线性关系;方法检出限为1.5×10-7mol/L。本方法针对Fe3+、Co2+、Cu2+等主要基体金属元素允许量低的问题,采用25%的2-羟基-4-仲辛氧基二苯甲酮肟(N530)磺化煤油萃取回收滤液中的Ni2+,镍回收率达到99%以上;赤泥中痕量镍的测定结果与催化光度法相符,加标回收率为98.3%-104.2%。  相似文献   

人体乳腺癌矿化的同步辐射研究     

孟繁露  李源  李艳  王长秋  鲁安怀  梅放 《岩石矿物学杂志》2015,34(6):957-962

同步辐射具有常规光源不可比拟的优良性能,可用于微量生物矿化样品的物相、结构、形貌和成分研究。本文利用基于同步辐射光源的X射线粉末衍射(SR-XRD)、傅立叶变换红外光谱(SR-FTIR)、X射线荧光分析(SR-XRF)和X射线三维成像,对人体乳腺癌矿化进行了表征。研究表明,乳腺癌矿化的主要矿物物相为碳羟磷灰石,含有Sr、Zn等微量元素,其中砂粒体矿化具有独特的分层结构。研究结果为乳腺癌的病理研究和诊断提供了矿物学参考信息。  相似文献   

Rapid delineation of subsurface petroleum contamination using the site characterization and analysis penetrometer system     

W. M. Davis  E. R. Cespedes  L. T. Lee  J. F. Powell  R. A. Goodson 《Environmental Geology》1997,29(3-4):228-237

 The Site Characterization and Analysis Penetrometer System (SCAPS) was used to investigate subsurface petroleum contamination at Aberdeen Proving Ground, Maryland. The SCAPS is a rapid site-screening tool developed by the Tri-Services (U.S. Army, Navy, and Air Force) to reduce the cost of installation restoration activities. The system, consisting of a geophysical cone penetrometer fitted with a laser-induced fluorescence petroleum sensor, is capable of simultaneous, real-time delineation of subsurface stratigraphy and petroleum contamination. Onsite processing of the SCAPS data allows three-dimensional visualization of both subsurface stratigraphy and petroleum contaminant distribution. The site investigation described herein successfully identified three distinct areas of subsurface petroleum contamination caused by leaking underground storage tanks containing No. 2 healing oil. The SCAPS petroleum sensor response was verified by obtaining 20 soil samples and performing onsite and conventional laboratory analyses for petroleum contaminants. Verification sample results indicate a strong correlation between the SCAPS fluorescence data and conventional measures of petroleum contamination. This investigation illustrates the capabilities of the SCAPS for rapid site characterization. Received: 27 November 1995 · Accepted: 11 December 1995  相似文献   

Dissolved organic carbon in the southern Baltic Sea: Quantification of factors affecting its distribution     

Karol Kuliński  Janusz Pempkowiak 《Estuarine, Coastal and Shelf Science》2008

During a cruise of r/v ‘Oceania’ in May 2006, seven vertical dissolved organic carbon (DOC) concentration profiles were produced against a background of CTD, chlorophyll a (chl a) and phaeopigment concentration profiles. The results indicate distinct vertical and spatial DOC fluctuations, ranging from 248 ± 7 μmol C dm⁻³ at 70 m depth at the westernmost station G/06 to 398 ± 5 μmol C dm⁻³ at 5 m depth at station A/06 in the western Gulf of Gdańsk. DOC concentrations were the highest at 10 m depth, where phytoplankton activity was relatively intensive, as reflected by the active chl a concentration distribution. DOC concentrations decreased towards the sea bottom.  相似文献